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Synfacts 2006(1): 0007-0007
DOI: 10.1055/s-2005-921654
DOI: 10.1055/s-2005-921654
Synthesis of Natural Products and Potential Drugs
© Georg Thieme Verlag Stuttgart · New York
Synthesis of (+)-Allocyathin
B. M. Trost*, L. Dong, G. M. Schroeder
Stanford University, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
16. Dezember 2005 (online)
![](https://www.thieme-connect.de/media/synfacts/200601/lookinside/thumbnails/10.1055-s-2005-921654-1.jpg)
Significance
(+)-Allocyathin is isolated from the fruit bodies of Cyathus earlei. It has antibacterial and antifungal properties. The challenge in the synthesis of Allocyathin is the construction of the characteristic angularly fused 5-6-7 tricyclic skeleton, containing a conjugated trienal motif and 1,4-anti stereocenters at each ring junction.