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Synthesis 2005(3): 374-380
DOI: 10.1055/s-2004-834938
DOI: 10.1055/s-2004-834938
PAPER
© Georg Thieme Verlag Stuttgart · New York
Preparation of Nitrogen-Containing 25-Membered Pentaolefinic Macrocycles: (E,E,E,E,E)-1,6,11,16,21-Penta(arylsulfonyl)-1,6,11,16,21-pentaazacyclopentacosa-3,8,13,18,23-pentaenes
Weitere Informationen
Received
26 July 2004
Publikationsdatum:
01. Dezember 2004 (online)
Publikationsverlauf
Publikationsdatum:
01. Dezember 2004 (online)
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Abstract
A stepwise preparation of a series of nitrogen-containing 25-membered pentaolefinic macrocycles is presented. The corresponding arenesulfonamides and trans-1,4-dibromo-2-butene served as precursors for the synthesis.
Key words
alkenes - heterocycles - macrocycles - sulfonamides
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It gave correct elemental analysis.
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References
Crystallographic data (excluding structure factors) for the structure in this paper has been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 230218. Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK [fax: +44 (1223)336033 or e-mail: deposit@ccdc.cam.ac.uk].