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Synlett 2002(7): 1118-1122
DOI: 10.1055/s-2002-32589
DOI: 10.1055/s-2002-32589
LETTER
© Georg Thieme Verlag Stuttgart · New York
Pd/C as a Highly Active Catalyst for Heck, Suzuki and Sonogashira Reactions
Weitere Informationen
Publikationsverlauf
Received
8 April 2002
Publikationsdatum:
07. Februar 2007 (online)


Abstract
A specially optimized air-stable Pd on activated carbon catalyst is demonstrated to be a highly active (TON up to 36,000), selective and convenient heterogeneous catalyst for CC couplings of aryl halides in Heck, Suzuki, and Sonogashira reactions. The Pd/C catalyst developed allows extremely low Pd concentrations (down to 0.0025 mol% for Heck coupling, 0.005 mol% for Suzuki coupling) and high conversions of aryl bromides within a few hours. Easy and complete Pd separation and recovery is possible.
Key words
aryl halides - catalysis - coupling - heterogeneous - palladium