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Synlett 1995; 1995(6): 599-602
DOI: 10.1055/s-1995-5025
DOI: 10.1055/s-1995-5025
letter
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Biocatalysis in Organic Synthesis. 6. First Use of an Acylase as Catalyst in the Irreversible Transacylation of Alcohols and Amines: Application to Selective Transformations1
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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The acylase from Aspergillus species catalyzes the acylation of alcohols and amines using vinyl acetate as irreversible acyl-transfer reagent. This is the first time that this enzyme has been employed to catalyze this kind of reaction. The method has been used in chemo-, regio-, and enantioselective transformations.
Alcohol - amine - kinetic resolution - acylase - selective transformations