Substitution of Arylsulfonyl Imidazolides by Hydrogen Peroxide: Aryl Sulfonic  Peracids as Oxidants for Olefins

Manfred Schulz; Ralph Kluge; Mareike Lipke

doi:10.1055/s-1993-22651

Subscribe to RSS

Please copy the URL and add it into your RSS Feed Reader.

https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000083.xml

Share / Bookmark

Facebook X Linkedin Weibo

Download PDF

Synlett 1993; 1993(12): 915-918
DOI: 10.1055/s-1993-22651

letter

© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Substitution of Arylsulfonyl Imidazolides by Hydrogen Peroxide: Aryl Sulfonic Peracids as Oxidants for Olefins

Manfred Schulz^* , Ralph Kluge, Mareike Lipke

^*Department of Chemistry, Martin-Luther-University Halle-Wittenberg, D-06217 Merseburg, Germany

Further Information

Publication History

Publication Date:
19 March 2002 (online)

PDF Download Permissions and Reprints All articles of this category

Aryl sulfonic peracids were generated in situ by reaction of corresponding arylsulfonyl imidazolides with H₂O₂ in alkaline medium.

The former were compared with other epoxidation agents with a variety of olefins. Compared to the arylsulfonyl chloride / KO₂ system, aryl sulfonic peracids showed different reactivity and selectivity towards olefins.