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Synlett 1993; 1993(6): 423-424
DOI: 10.1055/s-1993-22480
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Synthesis of Functional Oxazolidin-2-ones and Oxadiazin-2-ones in Two Steps from CO2 via Cyclic α-Methylene Carbonates

Jean-Marc Joumier* , Richard Grainger, Christian Bruneau, Pierre H. Dixneuf
  • *Laboratoire de Chimie de Coordination Organique, URA CNRS 415, Campus de Beaulieu, Université de Rennes, F-35042 Rennes, France
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Publication Date:
19 March 2002 (online)

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The direct synthesis of cyclic α-methylene carbonates from CO2 allows the access to optically active functional 4-hydroxy oxazolidin-2-ones by reaction with amino acids, to bis-oxazolidin-2-ones with ammonia, and to oxadiazin-2-ones with hydrazine.