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Synlett 1993; 1993(3): 215-216
DOI: 10.1055/s-1993-22407
DOI: 10.1055/s-1993-22407
letter
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Polyene Macrolactam Construction Using a Stille Vinyl-Vinyl Coupling Protocol: An Approach to the Antitumour Antibiotic Substance Leinamycin
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Publication History
Publication Date:
19 March 2002 (online)
A new approach to polyene macrolactam construction is described, based on an intramolecular Stille vinyl-vinyl coupling strategy, e.g. (10) → (12). The methodology is then applied to a synthesis of the macrolactam unit (17) found in the antitumour antibiotic substance leinamycin (1).