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Synthesis 2017; 49(05): 1109-1121
DOI: 10.1055/s-0036-1588900
DOI: 10.1055/s-0036-1588900
paper
o-Iodoxybenzoic Acid (IBX)–Iodine Mediated One-Pot Deacylative Sulfonylation of 1,3-Dicarbonyl Compounds: A Synthesis of β-Carbonyl Sulfones
Authors
Weitere Informationen
Publikationsverlauf
Received: 22. Juli 2016
Accepted after revision: 28. September 2016
Publikationsdatum:
26. Oktober 2016 (online)
Abstract
A combination of o-iodoxybenzoic acid (IBX) and a catalytic amount of iodine is found to promote a facile one-pot deacylative sulfonylation reaction of 1,3-dicarbonyl compounds with sodium sulfinates to yield β-carbonyl sulfones. The present method provides the target products bearing a wide variety of functional groups in one step and in good yields.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588900.
- Supporting Information (PDF)
-
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