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Synlett 2016; 27(20): 2836-2840
DOI: 10.1055/s-0036-1588883
DOI: 10.1055/s-0036-1588883
letter
The Preparation and Reactivity of 2-Bromo-3-(tri-n-butylstannyl)-1-propene
Weitere Informationen
Publikationsverlauf
Received: 13. Mai 2016
Accepted after revision: 25. August 2016
Publikationsdatum:
09. September 2016 (online)


Abstract
The preparation of 2-bromo-3-(tri-n-butylstannyl)-1-propene is described. This study characterizes the reactivity of 2-bromo-3-(tri-n-butylstannyl)-1-propene in SE′ reactions with aldehydes and includes a survey of radical reactions of 2-bromo-3-(tri-n-butylstannyl)-1-propene with α-bromocarbonyl compounds for C-alkylation.
Key words
organostannane preparation - bifunctional reagent - SE′ reactions - radical reaction - alkenyl bromidesSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588883.
- Supporting Information