Synlett 2016; 27(20): 2836-2840
DOI: 10.1055/s-0036-1588883
letter
© Georg Thieme Verlag Stuttgart · New York

The Preparation and Reactivity of 2-Bromo-3-(tri-n-butylstannyl)-1-propene

David R. Williams*
,
Akshay A. Shah
,
Dawn A. Brooks
,
Nicolas Zorn
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Publikationsverlauf

Received: 13. Mai 2016

Accepted after revision: 25. August 2016

Publikationsdatum:
09. September 2016 (online)


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Abstract

The preparation of 2-bromo-3-(tri-n-butylstannyl)-1-propene is described. This study characterizes the reactivity of 2-bromo-3-(tri-n-butylstannyl)-1-propene in SE′ reactions with aldehydes and includes a survey of radical reactions of 2-bromo-3-(tri-n-butylstannyl)-1-propene with α-bromocarbonyl compounds for C-alkylation.

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