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Synlett 2016; 27(13): 2024-2028
DOI: 10.1055/s-0035-1561654
DOI: 10.1055/s-0035-1561654
letter
Facile Synthesis of Stereodefined α-Iodovinyl Sulfoxides, Versatile Platform to Trisubstituted Olefins
Weitere Informationen
Publikationsverlauf
Received: 06. April 2016
Accepted after revision: 09. Mai 2016
Publikationsdatum:
01. Juni 2016 (online)


Abstract
Stereodefined α-iodovinyl sulfoxides bearing a sulfinyl group and an iodo group were prepared by a one-pot iodination/Horner–Wadsworth–Emmons reaction protocol. This reaction can be applied to a wide range of aldehydes, and further application was demonstrated.
Key words
sulfoxides - vinyl iodide - vinyl sulfoxides - sulfinyl phosphonates - trisubstituted olefins - olefination - Horner–Wadsworth–Emmons reaction - halovinyl sulfoxidesSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561654.
- Supporting Information