Synlett 2015; 26(17): 2332-2335
DOI: 10.1055/s-0034-1378789
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© Georg Thieme Verlag Stuttgart · New York

Catalytic Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes

Jianhui Chen
Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang, 310027, P. R. of China   eMail: luzhan@zju.edu.cn
,
Minyi Cao
Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang, 310027, P. R. of China   eMail: luzhan@zju.edu.cn
,
Biao Cheng
Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang, 310027, P. R. of China   eMail: luzhan@zju.edu.cn
,
Zhan Lu*
Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang, 310027, P. R. of China   eMail: luzhan@zju.edu.cn
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Publikationsverlauf

Received: 17. Mai 2015

Accepted after revision: 16. Juni 2015

Publikationsdatum:
23. Juli 2015 (online)


Abstract

Catalytic asymmetric hydrosilylation of 1,1-disubstituted alkenes has been summarized. The intramolecular reactions proceed efficiently in the presence of noble transition-metal rhodium. The highly enantioselective intermolecular processes are catalyzed by earth-abundant transition-metal iron.

 
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