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Synfacts 2011(12): 1322-1322
DOI: 10.1055/s-0031-1289382
DOI: 10.1055/s-0031-1289382
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Helical Macromolecular Ligand for Asymmetric Suzuki Coupling
T. Yamamoto, Y. Akai, Y. Nagata, M. Suginome*
Kyoto University and Japan Science and Technology Agency, Kyoto, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
18. November 2011 (online)
Significance
The catalytic asymmetric synthesis of molecules with axial chirality is an ongoing challenge in organic synthesis. This report describes the palladium-catalyzed asymmetric synthesis of biaryls using macromolecular polymeric phosphine ligands, which in some cases outperform conventional monomeric phosphine ligands.