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Synfacts 2011(12): 1316-1316
DOI: 10.1055/s-0031-1289336
DOI: 10.1055/s-0031-1289336
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Palladium-Catalyzed Enantioselective Fluorination of Allylic Halides
M. H. Katcher, A. Sha, A. G. Doyle*
Princeton University, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
18. November 2011 (online)
Significance
The palladium-catalyzed allylic fluorination is one of the first methods for the enantioselective synthesis of branched allylic fluorides. Following the authors’ recent report on allylic substitution of cyclic allyl chlorides (J. Am. Chem. Soc. 2010, 132, 17402), the methodology was extended to acyclic substrates.