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Synfacts 2011(10): 1111-1111  
DOI: 10.1055/s-0030-1261076
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Direct Suzuki-Miyaura Coupling of Phenol Derivatives via Mutual Activation

Contributor(s): Paul Knochel, Nadja M. Barl
D.-G. Yu, Z.-J. Shi*
Peking University, Beijing and Shanghai Institute of Organic Chemistry, P. R. of China
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Publication History

Publication Date:
20 September 2011 (online)

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Significance

Herein, a direct Ni-catalyzed Suzuki coupling of in situ generated sodium phenolates with aryl boroxines is reported. Key step is the formation of an aryl borate which simultaneously activates the two coupling partners.