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Synfacts 2011(10): 1105-1105
DOI: 10.1055/s-0030-1261059
DOI: 10.1055/s-0030-1261059
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Chiral Diamine-Polyoxometalate (POM) Acid Catalyzed Aldol Reaction
Q. Gao, S.-M. Lu, Y. Liu*, C. Li*
Dalian Institute of Chemical Physics and Graduate School of the Chinese Academy of Sciences, Beijing, P. R. of China
Further Information
Publication History
Publication Date:
20 September 2011 (online)
Significance
Aldol reactions utilizing long-chain aliphatic ketones are understudied; the authors developed a solvent-free aldol addition of aldehydes with long-chain aliphatic ketones catalyzed by a chiral diamine-polyoxometalate (POM) acid.