Hypervalent Bromine(III) Compounds: Synthesis, Applications, Prospects

Abstract

Hypervalent compounds play a prominent role in homogeneous oxidation catalysis. Despite the higher reactivity of hypervalent bromine compounds when compared to their isoelectronic iodine analogues, the corresponding λ³-bromanes are much less explored. This can be attributed to the discernible lack of convenient strategies for their synthesis. This short review highlights the available methods for the synthesis of various organo-λ³-bromanes, with a major focus on the recent developments and reactivities in the last few years. Additionally, limitations and future prospects of hypervalent bromine chemistry are discussed.

1 Introduction

2 Diaryl-λ³-bromanes

3 Dialkyl-λ³-bromanes

4 Dihetero-λ³-bromanes

5 Alkenyl-λ³-bromanes

6 Alkynyl-λ³-bromanes

7 Conclusion and Prospects

Key words

λ³-bromanes - hypervalent - bromine - iodine - bromonium - Br(III) - Oxidation

Publikationsverlauf

Eingereicht: 28. September 2021

Angenommen nach Revision: 21. Oktober 2021

Accepted Manuscript online:
21. Oktober 2021

Artikel online veröffentlicht:
30. November 2021

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