Hypervalent Bromine(III) Compounds: Synthesis, Applications, Prospects

Bethan Winterson; Tuhin Patra; Thomas Wirth

doi:10.1055/a-1675-8404

Synthesis, Table of Contents

CC BY 4.0 · Synthesis 2022; 54(05): 1261-1271
DOI: 10.1055/a-1675-8404

short review

Hypervalent Bromine(III) Compounds: Synthesis, Applications, Prospects

Bethan Winterson‡

,

Tuhin Patra ‡

,

Thomas Wirth ∗

Abstract

All articles of this category

Abstract

Hypervalent compounds play a prominent role in homogeneous oxidation catalysis. Despite the higher reactivity of hypervalent bromine compounds when compared to their isoelectronic iodine analogues, the corresponding λ³-bromanes are much less explored. This can be attributed to the discernible lack of convenient strategies for their synthesis. This short review highlights the available methods for the synthesis of various organo-λ³-bromanes, with a major focus on the recent developments and reactivities in the last few years. Additionally, limitations and future prospects of hypervalent bromine chemistry are discussed.

1 Introduction

2 Diaryl-λ³-bromanes

3 Dialkyl-λ³-bromanes

4 Dihetero-λ³-bromanes

5 Alkenyl-λ³-bromanes

6 Alkynyl-λ³-bromanes

7 Conclusion and Prospects

Key words

λ³-bromanes - hypervalent - bromine - iodine - bromonium - Br(III) - Oxidation

Full Text

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