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Synfacts 2010(5): 0615-0615  
DOI: 10.1055/s-0029-1219731
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Suzuki-Miyaura Coupling with Palladium(II) Phosphine Complexes on MNPs

Contributor(s): Yasuhiro Uozumi, Toshimasa Suzuka
S. Shylesh, L. Wang, W. R. Thiel*
TU Kaiserslautern, Germany
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Publication History

Publication Date:
22 April 2010 (online)

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Significance

A palladium(II) phosphine complex supported on magnetic nanoparticles (Pd@SMP) was prepared and applied to the Suzuki-Miyaura cross-coupling. The Suzuki-Miyaura coupling of bromobenzene with phenylboronic acid was performed with 1 mol% Pd of Pd@SMP to give ­biphenyl in 99% yield. The catalyst was separated from the reaction mixture by applying an external magnetic field.