DOI: 10.1055/s-00000131

Synfacts

Issue 11 · Volume 11 · November 2015 DOI: 10.1055/s-005-30319

Synform

A150
Zanda, Matteo: SYNFORM ISSUE 2015/11

Synthesis of Natural Products and Potential Drugs

z1121
All PDFs of this category
1121
Boron-Catalyzed N-Alkylation of Amines Using Carboxylic Acids
1122
Total Synthesis of Fijiolide A
1123
Total Synthesis of Epicolactone
1124
Synthesis of Cinacalcet by Asymmetric Hydroamination
1125
Synthesis of a Squaramide-Based CXCR2 Receptor Antagonist
1126
Synthesis of a Tetracyclic Indolenine that Represses β-Lactam Resistance
1127
Synthesis of Verruculogen and Fumitremorgin A
1128
Syntheses of (−)-Leucoridines A and C
1129
Synthesis of (+)-Rubriflordilactone A
1130
Synthesis of Hyperforin
1131
Total Synthesis of Multifidosides A–C
1132
Synthesis of BACE1 Inhibitors

Synthesis of Heterocycles

z1133
All PDFs of this category
1133
Synthesis of Spiroxindoles by Enantioselective [3+2] Annulation
1134
Efficient Synthesis of 5-Nitro-7-azaindole on a Kilogram Scale
1135
Substituted 7-Azaindoles by Directed Ortho Metalation/Nucleophilic Aromatic Substitution
1136
Synthesis of Polyfunctionalized 1,4,2-Oxathiazoles by Oxidative Cyclization
1137
Dihydroisocoumarin Synthesis by C–H ortho-Alkylation of Benzoic Acids
1138
Copper-Catalyzed Asymmetric Synthesis of Thiazolidine-2-imines
1139
Synthesis of Oxazoles from 2H-Azirines and Aldehydes by Photoredox Catalysis
1140
Synthesis of Indoles by Reductive Cyclization of ortho-Nitrostyrenes
1141
Ylidenemalononitrile Enamines in the Synthesis of Pyridines and Pyrones
1142
Synthesis of Azetidin-3-ones from Allenes by Oxidative Amination
1143
Synthesis of α-Hetaryl Nitriles by Asymmetric Reductive Cross-Coupling
1144
Synthesis of Borazaroquinolines and Borazaroisoquinolines
1145
Synthesis of Tetrasubstituted Furans by the Morita–Baylis–Hillman Reaction
1146
Substrate-Controlled C-2 Amination of Dichloropyrimidines with Tertiary Amines
1147
Asymmetric Synthesis of Heterocycle-Fused Butyrolactones

Synthesis of Materials and Unnatural Products

z1149
All PDFs of this category
1149
Give Me Five
1150
Fused Boracyclic Donor–Acceptor Materials
1151
Regioselective Double Acylation
1152
Quinoidal Bithiophenes Fluoresce in NIR
1153
A Smart Glue
1154
Buchwald’s Bullet
1155
Third Aryne’s the Charm
1156
New Oligomers by Radical Couplings for Delicious SWCNT Wraps
1157
Picky Zinc Porphyrazines: They Only Shine for Acids
1158
Formal SiH4 Chemistry Using Stable and Easy-to-Handle Surrogates
1159
Oxidation makes Dinaphtothiophenes Voracious for Electrons
1160
C,N Organoborons: New Dyes for Fluorescence Microscopy

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z1161
All PDFs of this category
1161
Palladium-Catalyzed Asymmetric Hydroesterification of Alkenylphenols
1162
Utility of a Fluoroiodomethylzinc Carbenoid in Fluorocyclopropanation
1163
Copper-Catalyzed Asymmetric 1,4-Addition of Alkylzirconocenes to Enones
1164
Copper-Catalyzed Asymmetric Synthesis of Spirobilactams
1165
Enantioselective Formation of All-Carbon Quaternary Stereocenters
1166
Enantioselective Nitrosocarbonyl Hetero-ene Reaction with Silyl Enol Ethers
1167
Copper-Catalyzed Enantioselective Synthesis of Carbo- and Heterocycles
1168
Iron-Catalyzed [2+2] Cycloadditions of Unactivated Alkenes
1169
Palladium-Catalyzed Asymmetric Carboamination of Alkenes
1170
Enantioselective Michael Addition to 2-Enoyl-pyridine N-Oxides
1171
Enantioselective Imine Reduction Catalyzed by Chiral Oxorhenium Complexes
1172
Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles
1173
Rhodium-Catalyzed Asymmetric 1,4-Addition to Conjugated Imino Esters
1174
Asymmetric Synthesis of Furo[3,4-b]indoles by Catalytic [3+2] Cycloaddition
1175
Enantio- and Diastereoselective Synthesis of γ-Amino Alcohols
1176
Asymmetric Synthesis of γ-Lactams by Hydroxoiridium/Chiral Diene Catalysis
1177
Asymmetric Iron(III)-Catalyzed Sulfa-Michael Addition of Thiols to Dienones
1178
Ligand-Controlled Regiodivergent Alkylboration of Alkenes with a Copper Catalyst
1179
Magnesium(II)-Catalyzed Asymmetric (4+1)-Annulation Reaction
1180
Enantioselective Borylation and Enantio-specific Cross-Coupling to Triarylmethanes
1181
Lewis Acid-Catalyzed [3+2] Asymmetric Annulation of Indoles with Aziridines
1182
Copper-Catalyzed Diastereoselective Synthesis of Hexahydropyrrolopyrroles
1183
Palladium(II)-Catalyzed Asymmetric Allylic Alkylation of Prochiral Enolates
1184
Kinetic Resolution of Vinyl Sulfoxides by Rhodium Catalysis
1185
Heck–Matsuda Desymmetrization of meso cis-4-Cyclopentene-1,3-diol
1186
Scandium-Catalyzed Diastereoselective [3+3] Cyclization
1187
Iron-Catalyzed Asymmetric Hydrophosphonylation of Aldehydes
1188
Redox Deracemization of Tetrahydroiso-quinolines
1189
Asymmetric Synthesis of Benzoxasiloles by Nickel Catalysis

Metal-Mediated Synthesis

z1191
All PDFs of this category
1191
Cobalt-Catalyzed Cyanation
1192
Oxidative Cross-Coupling of Boron Enolates
1193
Regioselective Aromatic C–H Borylation
1194
Coupling of Aryl Fluorosulfonates with Aryl Boronic Acids
1195
Copper-Catalyzed Oxidative Cross-Coupling of Tetrahydroisoquinolines
1196
Asymmetric 1,4-Addition of Arylboronic Acids to Cycloalkenes
1197
Stereospecific Coupling of Boronic Esters with Lithiated N-Heterocycles
1198
Pd-PEPPSI-IHeptCl-Catalyzed Cross-Coupling of Alkyl Zinc Reagents
1199
Dehydrogenative Borylation of Terminal Alkynes
1200
Cross-Coupling of Anisoles with a Nickel Catalyst
1201
Copper-Catalyzed Cyanation of Arylboronic Acids using Acetonitrile
1202
Palladium-Catalyzed Synthesis of Aryl Ketones from Amides
1203
Ligand-Controlled Stereoretentive Suzuki–Miyaura Cross-Coupling
1204
Silver-Mediated Direct O-Trifluoromethylation
1205
Aminoboration of Unfunctionalized Olefins

Organo- and Biocatalysis

z1207
All PDFs of this category
1207
Enzymatic cis-Dihydroxylation of Alkenes
1208
Rigid Cationic Multidentate Halogen Bond Donor Catalysts
1209
Switchable Organocatalytic Annulation Reactions
1210
1,4-Iodofunctionalizations of Conjugated Dienes
1211
Catalytic Heteroarene C-Alkylation with Alcohol-Derived Radicals
1212
Phosphoric Acid-Catalyzed Asymmetric Nitroso-Diels–Alder Reaction
1213
Synthesis of a Chiral β-Hydroxy-α-amino Acid by Using d-Threonine Aldolase

Polymer-Supported Synthesis

z1215
All PDFs of this category
1215
Aerobic Cross-Dehydrogenative Coupling with Nanoporous Gold
1216
Double Carbonylation of Aryl Iodides with Amines Using Palladium Nanoparticles
1217
Titania-Encapsulated Palladium Catalyst for Hydrodechlorination of Chlorophenols
1218
Synthesis of Benzimidazoles Catalyzed by an Ionic Liquid on Zinc Oxide Nanoparticles
1219
Suzuki–Miyaura Coupling Catalyzed by a Polymer-Bound Palladium–Phosphine Complex
1220
Oxidation of Hydrosilanes by Using Gold/Hydroxyapatite
1221
Continuous-Flow Kinetic Resolution by Lipase-Catalyzed N-Acetylation
1222
Hydrogenation of Nitroarenes by Using Co(0)-Co3O4/N-Doped Carbon Nanotubes
1223
Amidation of Carboxylic Acids Catalyzed by Polystyrene-Supported Triphenylphosphine
1224
Chitosan-Catalyzed Petasis Borono-Mannich Reaction
1225
Asymmetric Reduction of Imines Catalyzed by a Supported Organocatalyst
1226
One-Pot Synthesis of 2-Amino-4H-chromene-3-carbonitrile Derivatives
1227
Solid-Phase Synthesis of Quinolines by Using an Alkoxyamine Linker
1228
Hydrogenation with a Palladium/Ionic Liquid Catalyst on a Metal–Organic Framework
1229
Monodisperse Platinum Nanoparticles on Active Carbon for the Synthesis of 1H-Tetrazoles
1230
Solvent-Free Synthesis of Imidazoles by Using a Supported Heteropolyacid