DOI: 10.1055/s-00000131

Synfacts

Issue 07 · Volume 10 · July 2014 DOI: 10.1055/s-004-27193

Synform

A88
Zanda, Matteo: SYNFORM ISSUE 2014/07

Synthesis of Natural Products and Potential Drugs

z663
All PDFs of this category
0663
Enantioselective Total Synthesis of (+)-Nocardioazine A
0664
Synthesis of PSI-6130, the Nucleoside Core of Sofosbuvir
0665
Synthesis of an Estrogen Receptor Beta Agonist
0666
Synthesis of (+)-Liphagal
0667
Total Synthesis of (–)-Filiformin
0668
Synthesis of MET Kinase Inhibitor LY2801653
0669
Short Stereodivergent Synthesis of Three Aromadendrane Hydroazulenes
0670
Synthesis of (–)-Walsucochin B
0671
Synthesis of GK–GKRP Disruptor AMG-3969
0672
Synthesis of Efinaconazole
0673
Synthesis of Evacetrapib
0674
Total Synthesis of (−)-Lepenine
0675
Total Synthesis of Panaginsene
0676
Synthesis of DPP-4 Inhibitor Omarigliptin

Synthesis of Heterocycles

z677
All PDFs of this category
0677
Synthesis of Azepines by HSbF6-Catalyzed Cycloaddition of Aziridines with Acetylenes
0678
F3C-Containing Phenanthridines by Palladium-Catalyzed Intramolecular Cyclization
0679
Azoloquinazolines from ortho-Triazoloanilines Using an Isocyanide Linchpin
0680
Asymmetric Arylative Cyclization of 5-Alkynones with Arylboronic Acids
0681
Synthesis of β-Lactones via Intramolecular Rhodium-Catalyzed Cyclization
0682
Synthesis of 4-Alkyl-2,3-difluorobut-2-enolides by Cyclization
0683
Dihydro-oxazinones from Salicylamides
0684
3-Methylene-1-pyrrolines from N-Propargylic β-Enaminones
0685
Gold-Catalyzed Synthesis of Thiazoles via Methanesulfonyloxymethyl Ketones
0686
Palladium-Controlled Regioseletive Arylative Cyclization of Alkynols to Cyclic Ethers
0687
Hydroisoquinolines via Organocatalytic Diels–Alder/Nucleophilic Ring Closure
0688
Heterocyclic-Fused Benzopyrans by Heck-Type Reaction
0689
Synthesis of Trifluoromethyl-Containing Imidazoles
0690
Transition-Metal-Free Synthesis of Indazoles and Azaindazoles
0691
Triazolopyridines by Metal-Free Heteroannulation

Synthesis of Materials and Unnatural Products

z693
All PDFs of this category
0693
Surprising Stability: New Diaryltetraynes
0694
Novel Azaheptacenes from Two-Directional Cyclizations
0695
Amorphous Modular Polyamides via Ugi Four-Component Reaction
0696
A Copper-Catalyzed Dimerization Approach to Chrysene Derivatives
0697
Carboranes, Meet Carbenes; Carbenes, Meet Carboranes
0698
Direct Functionalization of Thiophene-Fused Borepins
0699
Fluoranthenes and Acenes Synthesized from Diol–Diene Cycloaddition
0700
Oligonaphthofurans: Molecular Fans
0701
The Return of Tetravinylethylene
0702
Nitrogen at the Center: Tristriazolotriazines from Tetrazoles
0703
‘ROMPing Around’: Paracyclophane Monomers for Poly(para-phenylenevinylene)s
0704
A Simplified Synthesis of Siloles

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z705
All PDFs of this category
0705
Gold(I)-Catalyzed Asymmetric Cycloadditions
0706
Ligand-Controlled Palladium-Catalyzed E- and Enantioselective Allylic Alkylation
0707
Chiral Triarylmethanes via an Enantiospecific Palladium-Catalyzed Cross-Coupling
0708
Spirocyclization in Air Catalyzed by an Iron-Salen Complex
0709
Asymmetric Ring Opening–Cross-Metathesis of Cyclobutene-diols
0710
Indolines via Asymmetric Copper-Mediated Inverse-Electron-Demand Aza-DA Reaction
0711
Borylation of Chiral Imines Catalyzed by Copper(II)
0712
Nickel-Catalyzed Enantioselective Nitro-Mannich Reaction of Isatin Derivatives
0713
Gold-Catalyzed Ring-Expanding Cycloisomerization of 1,5-Enynes
0714
Asymmetric Allylic Amination of Allylic Esters Catalyzed by Palladium
0715
Ruthenium–Porphyrin-Catalyzed trans-Selective Octalone Synthesis
0716
Synthesis of Enantioenriched Amines via an Asymmetric Palladium-Catalyzed Arylation
0717
Enantioselective Cobalt-Catalyzed Synthesis of [18F]Fluorohydrins for Use as PET Tracers
0718
A Copper-Catalyzed Oxidative Povarov Reaction Towards Polycyclic Amines
0719
Asymmetric Copper-Catalyzed Dynamic Kinetic Reactions of Aminocyclopropanes
0720
Gold-Catalyzed Synthesis of Heteroaryl Atropisomers
0721
Asymmetric Hydroamination Catalyzed by Zinc/Zirconium
0722
Asymmetric Tandem Alkylation–π-Allylation of α-Imino Esters
0723
Asymmetric Alkene Diamination Catalyzed by Copper
0724
Copper-Catalyzed Asymmetric 1,6-Selective Borylation of Dienones and Dienoates
0725
Asymmetric Reductive Allylations Catalyzed by Nickel(II)
0726
Asymmetric Conjugate Cyanation Catalyzed by Magnesium
0727
Enantioselective Michael Addition of Nitroalkenes Using a Cobalt Complex
0728
Allylsilanes in Asymmetric Inverse-Electron-Demand Hetero-DA Reactions
0729
Asymmetric Allylic Substitution Catalyzed by Pd−Thioether−Phosphite
0730
Enantioselective Azahelicenes via Intramolecular Hydroarylation of Alkynes
0731
Copper(II)-Catalyzed Silylation of Activated Alkynes
0732
Asymmetric Ruthenium-Catalyzed Hydrogenation of Trifluoromethyl Ketimines
0733
Copper-Catalyzed Intermolecular Three-Component Oxyarylation of Allenes

Metal-Mediated Synthesis

z735
All PDFs of this category
0735
Iron-Catalyzed Direct Arylation Using a Triazole Directing Group
0736
The Remarkable Role of Salt in the Cross-Coupling of Arylzincs
0737
C–H Zincation of (Hetero)Arenes Followed by Copper-Catalyzed Amination
0738
Stereocontrolled Synthesis of β-Hydroxy-α-Amino Acid Derivatives
0739
Synthesis of Enantioenriched α-Bromo-α-Fluoro-β-Lactams
0740
The Versatility of Ynimines
0741
Trifluoromethylthiolation of Diazoesters
0742
α-Amino Acid Synthesis from CO2 and N-Acyl-N,O-acetals
0743
Selective Addition of Organometallics to 3-Geminal Bis(silyl) N-Acyl Pyridinium
0744
A Novel Oxacycle Synthesis
0745
BF3-Mediated Synthesis of Amides
0746
Palladium-Catalyzed Hydrofluorination of Alkenylarenes
0747
Iron-Catalyzed Friedel–Crafts-Type Alkylation of Secondary Alcohols
0748
Titanium(III)-Catalyzed Acyloin-Type Cross-Coupling
0749
Trifluoromethylthiolation of Benzofuranes and Benzothiophenes

Organo- and Biocatalysis

z751
All PDFs of this category
0751
Oxidative α-Amination of β-Ketocarbonyls Catalyzed by a Primary Amine
0752
A Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis
0753
Catalytic Asymmetric Synthesis of 8-Oxabicyclooctanes
0754
Organocatalytic Asymmetric Trifluoromethylthiolation of Oxindoles
0755
Photoredox Organocatalytic Anti-Markovnikov Hydroamination of Alkenes
0756
Catalytic Enantioselective [2+2] Photocycloaddition of Alkenylcoumarins
0757
Enantioselective Friedel–Crafts Reaction of Furylacetones
0758
Brønsted Acid Catalyzed Oxidative Addition of Ketone Radicals to Olefins
0759
Tetrahydroisoquinolines via Asymmetric Aminocatalytic [3+2] Cycloaddition
0760
Asymmetric Catalysis on the Nanoscale
0761
Organocatalytic Synthesis of Atropisomers
0762
Formal [5+3] Cycloaddition via Cascade Dienamine–Dienamine Catalysis

Polymer-Supported Synthesis

z763
All PDFs of this category
0763
Pyranopyrazole Synthesis with Iron Oxide Nanoparticles
0764
Synthesis of Chiral Phthalides Using a Silica-Supported Rhodium Catalyst
0765
Oxidation of Secondary Alcohols with UiO-66-Cr MOF Catalyst
0766
C–N, C–O, and C–C Bond-Forming Reactions with NiFe2O4 Nanoparticles
0767
S-Arylation of Thiophenols with Aryl Halides Using Pdnp-nSTDP
0768
α-Alkylation of Ketones with Trialkylamines Using Palladium on Carbon
0769
1,4-Hydrogenation of α,β-Unsaturated Carbonyls with [Au]-TPDI-Rh
0770
Asymmetric Addition and Hydrogenation Using BINAP-MOF
0771
Amidation of Aryl Halides with Isocyanides Catalyzed by PS-Pd-NHC
0772
Transfer Hydrogenation of Nitroarenes with N2H4·H2O Using SS-Rh Nanoparticles
0773
Synthesis of Substituted Benzoxazoles Using CuFe2O4 Nanoparticles
0774
Mukaiyama Aldol Reaction Using Ion-Exchanged Montmorillonite Clay
0775
Unsymmetrical Diyne Synthesis via Solid-Phase Glaser–Hay Coupling
0776
Heck and Sonogashira Reactions Using PVC-Supported Palladium Nanoparticles
0777
Synthesis of Alkynyl Chalcogenides Catalyzed by Magnetite Nanoparticles

Erratum

0778
Grüning, W. R.; Siddiqi, G.; Safonova, O. V.; Copéret, C.: Direct Borylation of Arenes Catalyzed by Ir(I)-bpy-PMO