DOI: 10.1055/s-00000131

Synfacts

Issue 03 · Volume 10 · March 2014 DOI: 10.1055/s-004-26468

Synform

A31
Zanda, Matteo: SYNFORM ISSUE 2014/03

Synthesis of Natural Products and Potential Drugs

z225
All PDFs of this category
0225
Synthesis of (–)-Oseltamivir
0226
Total Synthesis of (–)-Angiolam A
0227
Synthesis of (–)-Calyciphylline N
0228
Total Synthesis of (±)-Yezo’otogirin C
0229
Synthesis of (–)-Ophiodilactones A and B
0230
Synthesis of a Bile Acid Transporter Inhibitor
0231
Synthesis of the β-Lactamase Inhibitor MK-7655
0232
Syntheses of Leuconolam–Leuconoxine–Mersicarpine Group Indole Alkaloids
0233
Total Synthesis of Sandresolide B and Amphilectolide
0234
Synthesis of a TRPV1 Antagonist
0235
Synthesis of (–)-Lasonolide A
0236
Synthesis of an HCV Replicase Inhibitor
0237
Synthesis of the Four Stereoisomers of Mefloquine

Synthesis of Heterocycles

z239
All PDFs of this category
0239
Intramolecular Ene Synthesis of 3-Pyrrolines
0240
Spiroaminals and Spiroketals via Au/La and Au/Y Relay Catalysis
0241
Synthesis of Pyrazoles via Nickel-Catalyzed Cyclotrimerization
0242
Synthesis of Oxazolones by a β-Selective Oxidative Heck Coupling
0243
Iridium-Catalyzed Route to Enantioenriched Tertiary Alcohols and Thioethers
0244
Synthesis of Dihydroimidazoles and Quinazolinones via C–H Amination
0245
Multicomponent Synthesis of Aza-Dibenzazepines Catalyzed by Rh/Pd
0246
Synthesis of 3,5-Diphenyl-1H-pyrazoles by Mechanochemical Ball Milling
0247
Synthesis of 1,3-Oxazin-6-ones from Enamides Catalyzed by Palladium
0248
1,3-Cycloaddition Route to 1,2,3-Triazoles Catalyzed by Copper
0249
Variation of the Pictet–Spengler Synthesis of Tetrahydrocarbolines
0250
Gold-Catalyzed Synthesis of Tetrazoles from Alkynes
0251
Synthesis of 3H-Pyrrolo[2,3-c]quinolin-4(5H)-ones Using ToSMIC Derivatives
0252
Substituted α-Amino-β-Lactams via Sequential C–H Arylation/C–H Amidation
0253
Diastereoselective Synthesis of Dibenzo[c,e]azepines

Synthesis of Materials and Unnatural Products

z255
All PDFs of this category
0255
‘Chalc’ing up a New Sumanene
0256
Stable Boranes with a Thiophene Linker
0257
Triarylmethanes Made to Order
0258
An ‘Ene’-credible Cascade
0259
A New SF4-Building Block
0260
A Radical Protection
0261
Terazulene: A Head-to-Tail Oligomer of Azulene
0262
A Cascade Cycloaddition Approach to Perylenes
0263
Can You exo-dig It? Radical-Cascade Synthesis of Polycyclic Frameworks
0264
Nothing Azaborine About It: One Step to Functionalized Azaborines
0265
Site-Selective Polycyclic Thiophenes From Alkynes via C–H Activation
0266
Gigantic Cyclic Poly(carbosiloxane)s

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z267
All PDFs of this category
0267
trans-Selective Hydroboration of Internal Alkynes Catalyzed by Ruthenium
0268
Chiral Pyridazines via Copper-Catalyzed Asymmetric Hetero-Diels–Alder Reaction
0269
Tandem Enantioselective Zinc-Promoted Reaction
0270
Allylsilanes via Tandem C–H Insertion–Decarboxylative Rearrangement
0271
Asymmetric Sonogashira Coupling Catalyzed by a Palladium Complex
0272
Synthesis of Tropanes through Asymmetric [3+2] Cycloaddition
0273
β-Tetralones and Benzobicyclo-[2.2.2]octanones via C–C Bond Cleavage
0274
Enantioselective Synthesis of Quaternary Succinimides Catalyzed by Palladium(II)
0275
Enantioselective Cyclative Acetoxylation Catalyzed by Palladium
0276
Palladium-Catalyzed Asymmetric Allylic Alkylation of Ketones
0277
Palladium-Catalyzed Enantioselective Desymmetrization of Bicyclic Hydrazines
0278
Magnesium-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition
0279
Domino Rhodium(III)-Catalyzed Hydroarylation–Lactonization
0280
Asymmetric Hydrogenolysis of N-Sulfonyl Amino Alcohols Catalyzed by Palladium
0281
Isochromenes Synthesis by Cyclization and Asymmetric Transfer Hydrogenation
0282
Intramolecular Allylic Alkylation by Iridium Catalysis
0283
Trisubstituted Monofluoroalkenes via Rh-Catalyzed Allylic C–F Bond Activation
0284
Asymmetric Monoborylation of Alkenylsilanes by Copper Catalysis
0285
Asymmetric Arylation of α-Keto Esters by Rhodium Catalysis
0286
Asymmetric O-Arylation by Palladium Catalysis
0287
Thiourea-Catalyzed Enantioselective Monofluoromethylation of Aldehydes
0288
Hydroalkynylation of Norboradienes by Rhodium Catalysis
0289
Asymmetric Addition of Acetonitrile to N-Thiophosphinoylimines by Copper Catalysis
0290
Chiral Amino Alcohols via a Palladium-Catalyzed Asymmetric Allylic Amination
0291
C–H Functionalization of Pyrroles Catalyzed by Palladium(II) and Phosphate
0292
Highly Stereoselective Manganese-Catalyzed Epoxidation of Styrenes and Δ5-Steroids
0293
Enantioenriched Cyclic Compounds by Allylic Alkylation and Metathesis
0294
Ruthenium-Catalyzed Asymmetric Hydrogenation of α,β-Unsaturated Ketones
0295
Transfer of Chirality for Synthesis of Bicyclo[5.3.0]decatrienes
0296
Direct C–O Arylation Catalyzed by Nickel

Metal-Mediated Synthesis

z297
All PDFs of this category
0297
Palladium-Catalyzed Linear-Selective Negishi Cross-Coupling of Allylzinc Halides
0298
Tandem Asymmetric Conjugate Addition –Enolate Trapping with Cyclic Enones
0299
α-Trifluoromethylated Alkylboron Compounds: Synthesis and Applications
0300
Titanium Ethoxide Mediated Synthesis of N-Acyl-N,O-acetals
0301
Synthesis of Acridine Derivatives by ZnCl2-Promoted Intramolecular Cyclization
0302
Methylation and meta Arylation of 3-Phenylpropanoic Acid Derivatives
0303
AgF-Mediated Homocoupling Reaction of β,β-Difluorostyrene Derivatives
0304
Arylthio–Metal Exchange Alkylation of α-Arylthioalkanenitriles
0305
Knochel, Paul; Klatt, Thomas: Zinc-Initiated Addition and Cascade Reactions of Alkynes
0306
Zinc-Catalyzed Borylation of Aryl Halides and Borylzincation of Benzynes
0307
Coupling of Arylzinc Reagents with Aryl and Alkenyl Halides
0308
Azomethine Imines by Intramolecular Cycloaddition Reaction
0309
Aldol Reaction with Super Silyl Haloacetate
0310
Preparation of a Trifluoromethyl Copper Reagent from Trifluoromethyl Ketones
0311
Chelation-Controlled Addition of Dialkylzinc Reagents to Aldehydes

Organo- and Biocatalysis

z313
All PDFs of this category
0313
Organocatalysis with Carbocations
0314
Oxidative Cross-Coupling in Asymmetric Aminocatalysis
0315
Arylation of Benzylic Ethers Using a Thiol Catalyst
0316
Enantioselective trans-Dihydroxylation of Styrenes via Cascade Biocatalysis
0317
Chiral DMAP Catalyzed Desymmetrization of meso Primary Diols
0318
Organocatalytic Enantioselective Cascade Aza-Michael–Michael Addition
0319
A General Aminocatalytic Protocol for the Synthesis of Aldimines

Polymer-Supported Synthesis

z321
All PDFs of this category
0321
A Silicon Nanowire Array Stabilized Palladium-Nanoparticle Catalyst
0322
α-Aminoxylation of Ketones with TEMPO Using Cu/SiO2-Fe
0323
Asymmetric Oxidation of Sulfides Using a Chiral Copper MOF
0324
Suzuki–Miyaura Coupling with SiliaCat DPP-Pd
0325
Oxidative Amidation of Primary Alcohols and Amines Using Au/HAP
0326
Synthesis of Benzoquinazolinones Using a Brønsted Acidic Ionic Liquid
0327
Pd/Al2O3-Catalyzed Hydrogenation Using H2 Micro- and Nanobubbles
0328
Synthesis of Imidazole, Thiazole, and Oxazole Derivatives with Nano-CeO2
0329
Asymmetric 1,3-Dipolar Cycloaddition with Imidazolidinone–Fe3O4 NPs
0330
Solvent-Free Ring Opening of Epoxides Using a Bismuth Complex
0331
The Crystal Plane Effect in the Au/CeO2-Catalyzed Alcohol Oxidation
0332
Disilylation of Terminal Alkynes with Au/TiO2