DOI: 10.1055/s-00000131

Synfacts

Issue 01 · Volume 9 · January 2013 DOI: 10.1055/s-002-24264

Synform

A1
Zanda, Matteo: SYNFORM ISSUE 2013/01

Synthesis of Natural Products and Potential Drugs

z1
All PDFs of this category
0001
Total Synthesis (±)-Garcibracteatone
0002
Synthesis of (–)-Oseltamivir Phosphate
0003
Synthesis of (+)-Lithospermic Acid
0004
Total Synthesis of Communesin F
0005
Synthesis of a p38 Kinase Inhibitor
0006
Synthesis of Candesartan Cilexetil
0007
Total Synthesis of (–)-Lycoposerramine-S
0008
Synthesis of (–)-Leiodermatolide
0009
Synthesis of TAK-733
0010
Synthesis of a Glucokinase Activator
0011
Synthesis of (R)-Rolipram
0012
Synthesis of Pregabalin
0013
Synthesis of Maxipost
0014
Synthesis of Akt Inhibitor GDC-0068
0015
Total Synthesis of the Dimeric Sarpagine Indole Alkaloid P-(+)-Dispegatrine
0016
Formal Syntheses of (±)-Laurefucin and (±)-E- and (±)-Z-Pinnatifidenyne
0017
Total Synthesis of Manzamine A and Related Alkaloids

Synthesis of Heterocycles

z19
All PDFs of this category
0019
Isatoic Anhydrides via C–H Activation
0020
Access to Quaternary Amino Acids via Dynamic Kinetic Resolution of Azlactones
0021
Synthesis of 3-Fluoropyrazoles from 2-Trifluoromethyl-1-alkenes
0022
A C–O/C–N Coupling Route to 1,4-Benzoxazines
0023
Organocatalytic Synthesis of Chromans and Benzopyrano[3,4-c]pyrrolidine
0024
De Novo Synthesis of Pyridones From Enaminones and Alkynes
0025
Synthesis of Pyrimidines from Propargylic Hydroxylamines
0026
Palladium-Catalyzed C–N/C–C Coupling Route to Substituted Indoles
0027
Iridium-Catalyzed Synthesis of Substituted Piperazines
0028
Iron-Catalyzed Synthesis of Pyrazoles from Hydrazones
0029
Phenyliodine(III) Diacetate-Promoted Synthesis of Benzimidazoles
0030
Palladium-Catalyzed Synthesis of Benzo[b][1,4]oxazepines
0031
Pd-Catalyzed Synthesis of Indeno[1,2-c]chromenes from 2-Alkynylhalobenzenes
0032
Palladium-Catalyzed Three-Component Synthesis of Oxazolines and Oxazines
0033
Synthesis of Heterocyclic Triquinanes via Sequential Radical Cyclizations

Synthesis of Materials and Unnatural Products

z35
All PDFs of this category
0035
Depolymerization Kinetics of Self-Immolative Polymers
0036
Redox-Switchable Cavitands: Molecular Grippers
0037
Precisely Defined Electron-Rich Oligopyrroles
0038
Large Stokes Shift from Triazine–o-Phenol Dyes
0039
Formation of an Unusual Four-Membered Nitrogen Ring
0040
Intermolecular Reactions of Gold–Vinylidene Complexes
0041
Shape Matters: Creating Amorphous Semiconductors
0042
Nitrogen-Free [18]Porphyrinoids in Two Steps
0043
Tuning The Quantum Yield of Fluorescent 2,5-Disubstituted-1,3a,6a-triazapentalene
0044
Synthesis of New Borolylbenzenes
0045
Electron-Acceptor Pentacene Derivative
0046
C–N Bond Formation Through a Single-Electron Transfer Pathway
0047
Poly(phenylacetylene)s with Pendant Sulfonamide Receptors for Anion Detection

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z49
All PDFs of this category
0049
Enantioselective Baeyer-Villiger Oxidation
0050
Palladium-Catalyzed Asymmetric Addition of Alkylazaarenes to Imines and Nitroalkenes
0051
Chiral Cp Ligands in Rhodium-Catalyzed Asymmetric C–H Functionalization
0052
Rhodium-Catalyzed Asymmetric Vinylogous Addition to Vinyldiazoacetates
0053
Cationic Gold-Catalyzed Cyclization of Diynamides
0054
Iron-Catalyzed Asymmetric Transfer Hydrogenation of Ketimines
0055
Palladium-Catalyzed Enantioselective Arylation of α-Imino Esters
0056
Copper-Catalyzed Enantioselective Incorporation of Ketones to Hemiaminals
0057
Rhodium-Catalyzed Enantioselective Hydroamination of Allenes
0058
Palladium-Catalyzed Enantioselective Aza-Morita–Baylis–Hillman Reaction
0059
Ruthenium-Catalyzed Asymmetric Hydrogenation of β‑Ketophosphonates
0060
Homopropargylic Ether Rearrangement via Gold Catalysis
0061
Palladium-Catalyzed Asymmetric Formal [3+2] Cycloaddition
0062
Asymmetric Ruthenium-Catalyzed Transfer Hydrogenation of Ketones
0063
Mechanistic Study of Palladium-Catalyzed Wacker-Type Cyclizations
0064
Access to 1,3-Enynes by Pd(II)-Catalyzed Dehydrogenative Olefination
0065
Artificial Rh(III)–Metalloenzyme-Catalyzed Asymmetric C–H Activation
0066
Enantioselective Copper-Catalyzed Borylative Aldol Cyclizations
0067
In Situ Aldehyde Enolate Formation by Rhodium-Catalyzed Isomerization
0068
A Rhodium(I)-Catalyzed Silylformylation–Crotosilylation–Tamao Oxidation
0069
Cobalt-Catalyzed [3+2] Cycloaddition of Alkynes with Cyclic Enones
0070
Scandium-Catalyzed Asymmetric Reduction with Potassium Borohydride
0071
Enantioselective Iridium(I)-Catalyzed Allylation of Sodium 2-Aminobenzenethiolates
0072
Palladium-Catalyzed Direct Arylation of Chromium-Activated Benzylic C–H Groups
0073
Negishi Reaction of Racemic Benzylic Bromides and Alkylzinc Reagents
0074
Asymmetric Synthesis of α,β-Thioepoxy Carbonyls by Rhodium Catalysis
0075
Nickel-Catalyzed Synthesis of γ-Fluorinated Homoallylic Alcohols
0076
Zink-Catalyzed Synthesis of Coumarin Derivatives by Asymmetric Michael Reaction
0077
Copper-Catalyzed Asymmetric Mannich Reaction of Glycine Imines
0078
Cobalt-Catalyzed Cross-Coupling of 1-Bromo Glycosides and Grignard Reagents

Metal-Mediated Synthesis

z79
All PDFs of this category
0079
Ruthenium-Catalyzed Generation of N-Unsubstituted Imines
0080
Pd-PEPPSI-IPentCl – Selective Coupling of Secondary Organozinc Nucleophiles
0081
Palladium-Catalyzed β-Arylation of α-Amino Esters
0082
Enantioselective Fluoroallylboration of Aldehydes
0083
Carboxylation of Unprotected Indole Derivatives with Carbon Dioxide
0084
Preparation and Rearrangement of N‑Vinyl Nitrones
0085
Synthesis of Phenanthridine Derivatives via Oxidative Cyclization
0086
Direct Amination of Alkyl and Aryl Pinacol Boronates
0087
Rhodium-Catalyzed Synthesis of Diaryl Sulfides Using S8/Organopolysulfides
0088
Iron-Catalyzed Hydromagnesiation of Diarylalkynes and Diynes
0089
Pentafluorinated β-Hydroxy Ketone Synthesis via Lithium-Mediated Aldol Reaction
0090
Fluorination of Nickel(II)–Aryl Complexes with [18F]Fluoride
0091
Ruthenium-Catalyzed ortho-Arylation and Alkenylation of N-Alkyl Benzamides
0092
Copper-Catalyzed Amination of Silyl Ketene Acetals with N-Chloroamines
0093
Metalation of 2-Phenylethyldimethylamine under Mild Conditions

Organo- and Biocatalysis

z95
All PDFs of this category
0095
Asymmetric Vinylogous Mukaiyama–Michael Reaction via Iminium Catalysis
0096
Thiourea-Catalyzed Asymmetric Cyanation of N-Boc Ketimines
0097
Organocatalytic Carbonyl-Olefin Metathesis Using a Hydrazine Catalyst
0098
Frustrated Lewis Pairs for Catalytic Hydrogenation of Allenes and Alkenes
0099
Organocatalytic Chemoselective Reduction of Phosphine Oxides to Phosphines
0100
Organocatalytic Synthesis of Substituted Furfuryl Alcohols and Amines
0101
Photocatalytic Anti-Markovnikov Hydroetherification
0102
Thiourea-Assisted Iminium Catalysis
0103
Asymmetric Protonation in Dienamine-Catalysis
0104
NHC-Catalyzed Annulation of Isatin N-Boc Ketimines and Enals
0105
NMR Characterization of Breslow Intermediates

Polymer-Supported Synthesis

z107
All PDFs of this category
0107
Nanoporous Gold Catalyst for the Selective Semihydrogenation of Alkynes
0108
Asymmetric Hydrogenation Using Polymer-Supported BINAP
0109
Asymmetric 1,4-Addition with a Chiral Calcium–Pybox Catalyst
0110
The Suzuki-Miyaura Coupling with Pd@Peptide
0111
Reduction of Nitroarenes Using In Situ Generated Iron Oxide Nanocrystals
0112
Silylation of Alcohol Derivatives with 1,2-Disilanes Catalyzed by Au/TiO2
0113
Annulation Reactions Catalyzed by Amberlite-Bound Hexafluorophosphate
0114
Asymmetric Aldol Reaction with BINAM-Sulfonyl Polymeric Organocatalyst
0115
Asymmetric Miyaura–Michael Reaction with Polymeric Rh/Ag Catalysts
0116
Polymer-Supported Iron(III) Catalyst for the Selective Oxidation of Toluene
0117
Aerobic Oxidation of Alcohols with Ru@PMO-IL
0118
Ullmann Homocoupling in Water or Molten TBAOAc with Gold Nanoparticles