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Synthesis 2002(6): 0717-0719
DOI: 10.1055/s-2002-25764
DOI: 10.1055/s-2002-25764
SHORTPAPER
© Georg Thieme Verlag Stuttgart · New York
Rhodium(I)-Catalyzed 1,2- and 1,4-Addition of Aryltriethoxysilanes to Carbonyl Compounds under Aqueous Basic Conditions
Further Information
Received
15 February 2002
Publication Date:
26 April 2002 (online)
Publication History
Publication Date:
26 April 2002 (online)
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Abstract
Aryltriethoxysilanes add to aldehydes and α,β-unsaturated carbonyl compounds in high yield in the presence of a rhodium(I) catalyst and aqueous sodium hydroxide.
Key words
rhodium - addition reactions - silicon - arylations - carbonyl compounds
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