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Synthesis 2019; 51(10): 2107-2115
DOI: 10.1055/s-0037-1612217
DOI: 10.1055/s-0037-1612217
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Silanediol Anion Binding and Enantioselective Catalysis
The National Science Foundation (1362030), the National Institutes of Health (1R35GM12480401), and Worcester Polytechnic Institute (WPI) are gratefully acknowledged for providing support for our studies. K.O. was supported by a fellowship from Yamagata University to study in the Mattson laboratory to complete these investigations. J.W.A. was supported by a WPI global scholars fellowship to complete investigations in the Kondo laboratory. J.H. is grateful for a WPI Summer Undergraduate Research Fellowship that supported her contribution to this project.Further Information
Publication History
Received: 11 January 2019
Accepted after revision: 14 January 2019
Publication Date:
12 March 2019 (online)
![](https://www.thieme-connect.de/media/synthesis/201910/lookinside/thumbnails/ss-2018-z0774-fa_10-1055_s-0037-1612217-1.jpg)
Abstract
Silanediols possess unique and complementary catalytic activity in reactions that are likely to proceed through anion binding. This article directly compares silanediols, thioureas, and squaramides in three separate anion-binding processes. The catalytic abilities of select members of each family are directly correlated to association constants.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1612217.
- Supporting Information
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