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Synlett 2019; 30(16): 1850-1854
DOI: 10.1055/s-0037-1610719
DOI: 10.1055/s-0037-1610719
synpacts
Nickel-Catalyzed Migratory Arylboration of Nonactivated Alkenes
Autor*innen
This work was supported by the National Natural Science Foundation of China (No. 21702151, 21871211) and the Fundamental Research Funds for Central Universities.
Weitere Informationen
Publikationsverlauf
Received: 06. Mai 2019
Accepted after revision: 29. Mai 2019
Publikationsdatum:
26. Juni 2019 (online)
◊ These authors contributed equally to this paper.
Abstract
An unprecedented nickel-catalyzed 1,n-arylboration (n >2) of terminal nonactivated alkenes has been developed. This reaction is the first example of a regioselective arylboration of terminal nonactivated alkenes and features high selectivity, wide functional-group tolerance, and operational simplicity. Remarkably, preliminary mechanistic studies indicated that an equilibrium of various nickel intermediates exists in this transformation, but bond formation is favored at the benzylic position.
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