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Synlett 2013; 24(19): 2472-2476
DOI: 10.1055/s-0033-1339871
DOI: 10.1055/s-0033-1339871
synpacts
Pd-Catalyzed sp2 C–H Hydroxylation with TFA/TFAA via Weak Coordinations
Further Information
Publication History
Received: 14 June 2013
Accepted after revision: 30 August 2013
Publication Date:
30 September 2013 (online)
Abstract
An efficient sp2 C–H hydroxylation has been developed for the synthesis of a wide range of functionalized phenols with aryl ketones, benzoates, benzamides, acetanilides and sulfonamides through palladium(II) catalysis. A trifluoroacetic acid (TFA)/trifluoroacetic anhydride (TFAA) co-solvent system serves as the oxygen source and is the critical factor for weak coordination promoted C–H activation.
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For general reviews on transition-metal-catalyzed C–H activation of arenes, see:
For illustrative transition-metal-catalyzed C–H activation of arenes, see:
For C–H activation through weak coordination, see:
For bystanding F+ oxidants, see:
For methane C–H oxygenation examples, see: