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Synthesis 2011(8): 1233-1242
DOI: 10.1055/s-0030-1259969
DOI: 10.1055/s-0030-1259969
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of (Diphenylphosphinoyl)methyl Vinyl Sulfides, Symmetric and Asymmetric Divinyl Sulfides from Bis[(diphenylphosphinoyl)methyl] Sulfide
Further Information
Received
28 December 2010
Publication Date:
24 March 2011 (online)
Publication History
Publication Date:
24 March 2011 (online)
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Abstract
Convenient Horner-Wittig-based synthetic approaches to the preparation of (diphenylphosphinoyl)methyl vinyl sulfides as well as symmetrically and unsymmetrically substituted divinyl sulfides, are described. The syntheses involve the use of the easily available bis[(diphenylphosphinoyl)methyl] sulfide as a common starting material and sodium hydride as base, in tetrahydrofuran.
Key words
sulfur - Wittig reaction - alkenation - ketones - aldehydes
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