Synlett 2011(8): 1081-1084  
DOI: 10.1055/s-0030-1259927
LETTER
© Georg Thieme Verlag Stuttgart ˙ New York

Magnetically Recoverable Pd/Fe3O4-Catalyzed Hiyama Cross-Coupling of Aryl Bromides with Aryl Siloxanes

B. Sreedhar*, A. Suresh Kumar, Divya Yada
Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology (Council of Scientific and Industrial Research), Hyderabad 500007, India
Fax: +91(40)27160921; e-Mail: sreedharb@iict.res.in;
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Publication History

Received 2 December 2010
Publication Date:
29 March 2011 (online)

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Abstract

This letter describes a simple and efficient method for the synthesis of biaryls by fluoride-free Hiyama cross-coupling of bromoarenes with aryl siloxanes using magnetically separable Pd/Fe3O4 as the catalyst under aqueous conditions. This methodology is applicable to wide range of aryl bromides and aryl siloxanes. High catalytic activity, ease of recovery using an external magnetic field and use of water as the solvent are additional eco-friendly attributes of this catalytic system. The catalyst was recycled five times without significant loss of catalytic activity.

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