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Synthesis 2009(7): 1081-1086
DOI: 10.1055/s-0028-1088012
DOI: 10.1055/s-0028-1088012
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
A Novel and General Method for the Formation of S-Aryl, Se-Aryl, and Te-Aryl Phosphorochalcogenoates
Further Information
Received
28 October 2008
Publication Date:
16 March 2009 (online)
Publication History
Publication Date:
16 March 2009 (online)
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Abstract
A new and general method for the synthesis of S-, Se-, and Te-aryl phosphorochalcogenoates (chalcogenophosphates) has been developed. S-P, Se-P, and Te-P bonds were formed by the coupling of readily available dialkyl phosphites with diaryl dichalcogenides at 30 ˚C in dimethyl sulfoxide in the presence of catalytic amounts of copper iodide and diethylamine. The reaction proceeded smoothly without exclusion of moisture or air.
Key words
Lewis acids - selenium - phosphorylation - sulfur - tellurium
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