Synthesis and Coordination Behavior of 9,10-Diarsatriptycene

Ryoto Inaba; Takashi Kikuchi; Hiroaki Imoto; Kensuke Naka

doi:10.1055/a-2112-9605

Synlett, Table of Contents

Synlett 2024; 35(04): 437-440
DOI: 10.1055/a-2112-9605

cluster

11th Singapore International Chemistry Conference (SICC-11)

Synthesis and Coordination Behavior of 9,10-Diarsatriptycene

Ryoto Inaba

^aFaculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

,

Takashi Kikuchi

^bRigaku Corporation, 3-9-12 Matsubara-cho, Akishima-shi, Tokyo 196-8666, Japan

,

Hiroaki Imoto∗

^aFaculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

^cFOREST, JST, Honcho 4-1-8, Kawaguchi, Saitama 332-0012, Japan

,

Kensuke Naka∗

^aFaculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

^dMaterials Innovation Lab, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

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Abstract

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Abstract

Herein, 9,10-diheterotriptycenes (DHTs) containing heavy pnictogens (Pn, Pn = As, Sb, and Bi) are synthesized without using the dangerous chemicals used in conventional synthetic methods: tert-butyllithium, organomercury reagents, or trichloroarsine. In particular, 9,10-diarsatriptycene is obtained in relatively high yield and is stable under oxidation and coordination reactions. Additionally, the gold chloride complex 9,10-diarsatriptycene forms a one-dimensional supramolecular polymer constructed through coordination and aurophilic interactions.

Key words

diheterotriptycene - pnictogen - practical synthesis - oxidation - coordination - supramolecular polymer

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