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DOI: 10.1055/a-1900-3563
Synthesis of Shape-Persistent meta-Arylene-Butadiynylene Macrocycles with a Different Ring Size
The research has been supported by the National Science Centre Poland (Grants UMO-2018/31/N/ST5/00450 and UMO-2018/31/B/ ST5/00899).
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Abstract
A series of meta-phenylene-butadiynylene macrocycles was obtained by homocoupling of terminal bis(ethynyl) precursors using Eglinton conditions. Cyclotetramers and cyclopentamers were isolated from the mixture. However, a hexameric analogue was synthesized using a step-by-step approach. Molecular structures of the resulting macrocycles obtained by X-ray single-crystal analysis manifest conformational diversity, indicating significant flexibility of the meta-arylene-butadiynylene macrocycle conjugated skeleton.
Key words
macrocycles - cross-coupling - Eglinton coupling - butadiynes - shape-persistent macrocyclesSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1900-3563.
- Supporting Information
Publication History
Received: 29 April 2022
Accepted after revision: 14 July 2022
Accepted Manuscript online:
14 July 2022
Article published online:
31 August 2022
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