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DOI: 10.1055/s-2008-1078687
Corrole: The Little Big Porphyrinoid
Publikationsverlauf
Publikationsdatum:
31. Juli 2008 (online)
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Abstract
In this account, the author describes the synthetic efforts of his group on the preparation and functionalization of corrole derivatives. The work started with β-alkylcorroles and continued with the preparation of 5,10,15-triarylcorroles. The peripheral functionalization of both the β-alkyl- and meso-triarylcorroles is described, together with several examples of the intriguing and unexpected reactivity of this deceptive macrocycle in these reactions.
1 Introduction
2 Starting with β-Alkylcorroles
3 meso-Substituted Corroles
4 Peripheral Functionalization of Corroles
4.1 Formylation
4.2 Bromination
4.3 Nitration
4.4 Demetalation
5 Isocorroles
6 Remarks and Future Work
Key words
corroles - porphyrinoids - tetrapyrroles - functionalization - complexes
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