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Synfacts 2007(12): 1260-1260
DOI: 10.1055/s-2007-991364
DOI: 10.1055/s-2007-991364
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York
A Controlling Neighbor
S. Motokucho, A. Sudo, T. Endo*
Kinki University, Fukuoka, Japan
Further Information
Publication History
Publication Date:
22 November 2007 (online)
![](https://www.thieme-connect.de/media/synfacts/200712/lookinside/thumbnails/10.1055-s-2007-991364-1.jpg)
Significance
Living polymerizations to produce highly functionalized polymers are not abundant. This polymerization produces a dithiocarbonate main chain and a carbamate pendant group. The structure of the polymer is precise and is free from other isomers that can be observed in systems that lack the stabilized cationic intermediates.