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Synfacts 2007(12): 1285-1285
DOI: 10.1055/s-2007-991349
DOI: 10.1055/s-2007-991349
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
C-S Bond Formation by Iron-Catalyzed Michael Addition of Thiols
M. Kawatsura*, Y. Komatsu, M. Yamamoto, S. Hayase, T. Itoh*
Tottori University, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. November 2007 (online)
![](https://www.thieme-connect.de/media/synfacts/200712/lookinside/thumbnails/10.1055-s-2007-991349-1.jpg)
Significance
The authors describe a carbon-sulfur bond-forming Michael addition. Chiral sulfur-containing compounds are useful for both organic and medicinal chemistry and access to these products remains an important task. The use of an iron-centered catalyst makes this a useful protocol due to the environmentally friendly nature of iron. Good to high enantioselectivities are obtained in this reaction.