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Synlett 2008(2): 297-298
DOI: 10.1055/s-2007-990952
DOI: 10.1055/s-2007-990952
SPOTLIGHT
© Georg Thieme Verlag Stuttgart · New York
Allyltributylstannane
Further Information
Publication History
Publication Date:
21 December 2007 (online)
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Introduction
Allyltributylstannane is a valuable reagent in organic synthesis. This reagent is a colorless liquid and stable towards air, heat, and hydrolysis. It is commercially available and has been widely used in organic synthesis as powerful reagent for C-C bond-forming reactions. Transmetallation, nucleophilic substitution, stereoselective carbonyl addition, and transition-metal- or radical-mediated substitution reactions have been accomplished using allyltributylstannane. [1] Although this reagent is mainly used in allylation reactions, other reactions such as cyclization and Diels-Alder reactions are also carried out using this reagent.
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