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Synfacts 2007(4): 0377-0377
DOI: 10.1055/s-2007-968315
DOI: 10.1055/s-2007-968315
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York
Growing Polymer Brushes on Gold
E. M. Benetti, S. Zapotoczny, G. J. Vancso*
University of Twente, Enschede, The Netherlands
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
23. März 2007 (online)
![](https://www.thieme-connect.de/media/synfacts/200704/lookinside/thumbnails/10.1055-s-2007-968315-1.jpg)
Significance
The authors synthesize a new iniferter (a single molecule that acts as an initiator, transfer agent and terminator during a polymerization), 1, and use it to grow poly(acrylamide) polymer brushes immobilized on a gold surface. The disulfide functionality of 1 anchors the iniferter onto the gold surface and the diethyldithiocarbamyl moiety allows one to control polymer chain length during the photopolymerization of N-isopropylacrylamide.