RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000131.xml
Synfacts 2007(3): 0287-0287
DOI: 10.1055/s-2007-968242
DOI: 10.1055/s-2007-968242
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Lanthanide-Pybox Catalyzed Mukaiyama Aldol Reaction
G. Desimoni*, G. Faita, F. Piccinini, M. Toscanini
Università di Pavia, Italy
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Februar 2007 (online)
![](https://www.thieme-connect.de/media/synfacts/200703/lookinside/thumbnails/10.1055-s-2007-968242-1.jpg)
Significance
In the further development of the Mukiayama aldol reaction catalyzed by box and pybox ligands originally pioneered by Evans, led the authors to find an alternative ligand-metal system to optimize enantioselectivity and yields. The authors studied lanthanide pybox complexes and demonstrate high yields and selectivities using scandium and lutetium.