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Synfacts 2006(12): 1207-1207  
DOI: 10.1055/s-2006-955601
Synthesis of Natural Products and Potential Drugs
© Georg Thieme Verlag Stuttgart · New York

Synthesis of (±)-Salviasperanol

Contributor(s): Philip Kocienski, Fiona Black
E. M. Simmons, R. Sarpong*
University of California, Berkeley, USA
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Publication History

Publication Date:
22 November 2006 (online)

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Significance

Salviasperanol belongs to the icetexane diterpene family of natural products. The key tricyclic intermediate G is synthesized using a Ga(III)-catalyzed cycloisomerization of enyne C.