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Synfacts 2006(12): 1238-1238
DOI: 10.1055/s-2006-949495
DOI: 10.1055/s-2006-949495
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Pd-Catalyzed Allylic Alkylation of Nitromethane and its Application
T. Nemoto, L. Jin, H. Nakamura, Y. Hamada*
Chiba University, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. November 2006 (online)
Significance
Several methods for asymmetric allylic alkylation exist which can introduce various nucleophiles such as nitrogen, sulfur and oxygen. This reaction is often plagued by side reactions or multiple alkylations. The authors describe the allylic alkylation of nitromethane and show its use in the synthesis of two natural products.