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Synfacts 2006(10): 1016-1016
DOI: 10.1055/s-2006-949366
DOI: 10.1055/s-2006-949366
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York
Synthesis of Polyvinylenephosphines
L. A. Vanderark, T. J. Clark, E. Rivard, I. Manners*, J. C. Slootweg, K. Lammertsma*
University of Toronto, Canada; University of Bristol, UK; Vrije Universiteit, Amsterdam, The Netherlands
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. September 2006 (online)
Significance
A polyvinylenephosphine was prepared by anionic ring-opening polymerization of a strained 1-phenyl-2,3-dimethylphosphirene, using a substoichiometric amount of n-BuLi as initiator. The polymer was synthesized in good yield and with a reasonably high molecular weight. Air-stable polymer samples were also obtained upon sulfurization of the polyvinylenephosphine with elemental sulfur.