RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000131.xml
Synfacts 2006(10): 1024-1024
DOI: 10.1055/s-2006-949284
DOI: 10.1055/s-2006-949284
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Bulky Chiral Ligand for Rh-Catalyzed Carbenoid Reactions
R. P. Reddy, G. H. Lee, H. M. L. Davies*
State University of New York, Buffalo, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. September 2006 (online)
Significance
The chiral catalyst Rh2[(S)-DOSP]4 is usually the best catalyst for reactions with donor/acceptor carbenoids. However, the new Rh2[(S)-PTAD]4 complex was shown to be an excellent back-up catalyst for cases where Rh2[(S)-DOSP]4 did not achieve satisfactory enantioselectivity.