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Synlett 2006(12): 1851-1854
DOI: 10.1055/s-2006-947345
DOI: 10.1055/s-2006-947345
LETTER
© Georg Thieme Verlag Stuttgart · New York
Carboxylic Phosphoric Anhydrides as a New Coupling Partner in Pd-Catalyzed Coupling Reactions: A New Ketone Synthesis
Further Information
Received
14 April 2006
Publication Date:
24 July 2006 (online)
Publication History
Publication Date:
24 July 2006 (online)
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Abstract
The Pd-catalyzed cross-coupling reactions of carboxylic phosphoric anhydrides with organoboronic acids or organostannanes afforded the corresponding ketones. The intramolecular Heck reaction was successful with carboxylic phosphoric anhydrides as a coupling partner.
Key words
palladium - cross-coupling - ketone - Suzuki reaction - Stille reaction
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