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Synfacts 2006(5): 0478-0478  
DOI: 10.1055/s-2006-934351
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York

Copper-Catalyzed 1,3-Dipolar Cycloaddition of Azomethyne Ylides with Nitroalkenes

Contributor(s): Mark Lautens, Yann Béthuel
X.-X. Yan, Q. Peng, Y. Zhang, K. Zhang, W. Hong, X.-L. Hou*, Y-D. Wu
Shanghai Institute of Organic Chemistry, P. R. of China
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Publikationsdatum:
21. April 2006 (online)

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Significance

The use of electronically diverse copper-P,N-ferrocene-based catalytic systems in the 1,3-dipolar cycloaddition of azomethine ylides to nitroalkenes allowed for the preparation of high enantiomerically pure pyrrolidine in a stereoselective manner.