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Synthesis 2006(4): 716-722
DOI: 10.1055/s-2006-926285
DOI: 10.1055/s-2006-926285
PAPER
© Georg Thieme Verlag Stuttgart · New York
A Simple Thiophosphate-Based Method for α-Alkylidenation of Lactones
Further Information
Received
28 July 2005
Publication Date:
11 January 2006 (online)
Publication History
Publication Date:
11 January 2006 (online)
Abstract
A variety of α-alkylidene lactones has been synthesized using a one-pot procedure based on the reaction of readily available thiophosphates with aldehydes under basic, mild conditions.
Key words
α-alkylidene lactones - lactones - thiophosphates - aldol reactions - stereoselectivity
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