Synlett 2006(1): 0109-0111  
DOI: 10.1055/s-2005-922771
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© Georg Thieme Verlag Stuttgart · New York

A New Method for the Synthesis of 2-Aryl-1H-benzimidazoles: Selenium-­Catalyzed Reductive N-Heterocyclization of Benzylidene(2-nitroaryl)amines with Carbon Monoxide

Yutaka Nishiyama*, Mayu Fujimoto, Noboru Sonoda*
Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka 564-8680, Japan
Fax: +81(6)63394026; e-Mail: nishiya@pcku.kansai-u.ac.jp;
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Publication History

Received 8 August 2005
Publication Date:
16 December 2005 (online)

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Abstract

The treatment of benzylidene(2-nitroaryl)amines, prepared by the reaction of o-nitro aniline and benzaldehydes, with carbon monoxide in the presence of a catalytic amount of selenium under basic conditions, afforded 2-aryl-1H-benzimidazoles in ­moderate to good yields.

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