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Synlett 2006(1): 0109-0111
DOI: 10.1055/s-2005-922771
DOI: 10.1055/s-2005-922771
LETTER
© Georg Thieme Verlag Stuttgart · New York
A New Method for the Synthesis of 2-Aryl-1H-benzimidazoles: Selenium-Catalyzed Reductive N-Heterocyclization of Benzylidene(2-nitroaryl)amines with Carbon Monoxide
Further Information
Publication History
Received
8 August 2005
Publication Date:
16 December 2005 (online)


Abstract
The treatment of benzylidene(2-nitroaryl)amines, prepared by the reaction of o-nitro aniline and benzaldehydes, with carbon monoxide in the presence of a catalytic amount of selenium under basic conditions, afforded 2-aryl-1H-benzimidazoles in moderate to good yields.
Key words
selenium - carbon monoxide - 2-aryl-1H-benzimidazole - benzylidene(2-nitroaryl)amine