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Synfacts 2006(1): 0038-0038
DOI: 10.1055/s-2005-921672
DOI: 10.1055/s-2005-921672
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Stereoselective Synthesis of Allylic Alcohols via [3,3]-Sigmatropic Rearrangement
E. E. Lee, R. A. Batey*
University of Toronto, Canada
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
16. Dezember 2005 (online)
![](https://www.thieme-connect.de/media/synfacts/200601/lookinside/thumbnails/10.1055-s-2005-921672-1.jpg)
Significance
Using a COP-Cl/AgOTFA catalyst system, (allyloxy)iminodiazaphospholidines can be converted into enantioenriched allylamines in an Overman-type rearrangement. E-Substituted substrates afford products of S configuration whereas Z-substituted substrates lead to R configuration in good to excellent yields and enantiomeric excesses.