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Synthesis 2005(7): 1178-1182
DOI: 10.1055/s-2005-861834
DOI: 10.1055/s-2005-861834
PAPER
© Georg Thieme Verlag Stuttgart · New York
Polyfunctionalized Aryllead Triacetates in a Cascade Synthesis of Tetracyclic Isochromanocoumarin-Type Compounds
Further Information
Received
14 December 2004
Publication Date:
21 February 2005 (online)
Publication History
Publication Date:
21 February 2005 (online)
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Abstract
The three-step one-pot α-arylation-annulation sequence leading to the reaction of 4-hydroxycoumarins with in situ generated 2-(bromomethyl)aryllead triacetates carried out in the presence of a combination of ortho-phenantroline-potassium tert-butoxide afforded tetracyclic benzo[b]pyran compounds in good to high yields.
Key words
4-hydroxycoumarins - arylboronic acids - aryllead triacetates - reductive ligand coupling reactions
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