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Synthesis 2003(18): 2882-2885
DOI: 10.1055/s-2003-44347
DOI: 10.1055/s-2003-44347
SPECIALTOPIC
© Georg Thieme Verlag Stuttgart · New York
A Convenient Method for Preparing Aromatic α,β-Unsaturated Ketones from α,β-Unsaturated Acyl Chlorides and Arylboronic Acids via Suzuki-Miyaura Type Coupling Reaction
Weitere Informationen
Received
22 September 2003
Publikationsdatum:
19. November 2003 (online)
Publikationsverlauf
Publikationsdatum:
19. November 2003 (online)
![](https://www.thieme-connect.de/media/synthesis/200318/lookinside/thumbnails/10.1055-s-2003-44347-1.jpg)
Abstract
Aromatic α,β-unsaturated ketones are synthesized efficiently by palladium-catalyzed cross-coupling reaction of arylboronic acids with α,β-unsaturated acyl chlorides in the presence of K3PO4 hydrate in toluene.
Key words
boron - catalysis - cross-coupling - ketones - palladium
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