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Synlett 2001; 2001(11): 1711-1714
DOI: 10.1055/s-2001-18081
DOI: 10.1055/s-2001-18081
letter
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Formation of Propargylic Stereocentres using Desymmetrised Alkyne Complexes
Further Information
Publication History
Publication Date:
29 October 2001 (online)
Addition of Grignard reagents to alkynyl aldehyde complexed bimetallic system proceeds with good to excellent stereocontrol.
asymmetric synthesis - chiral auxiliaries - transition metals - stereoselectivity - nucleophilic additions