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Synlett 2001; 2001(10): 1656-1658
DOI: 10.1055/s-2001-17473
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A Stereoselective Synthesis of 1-Acetyl-2-aminomethylcyclopropanes from Allylsulfonamides and Phenyl(alkynyl)iodonium Salts

Hee-Yoon Lee* , Yong-Han Lee
  • *Center for Molecular Design & Synthesis, Department of Chemistry and School of Molecular Sciences(BK21), Korea Advanced Institute of Science & Technology, Taejon 305-701, Korea; Fax + 82(42)8 69 83 70; E-mail: leehy@kaist.ac.kr
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Publication Date:
27 September 2001 (online)

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A versatile and stereoselective synthesis of 1-acetyl-2-aminomethyl cyclopropanes from the reaction of anions of tosylallylamines and phenyl(propynyl)iodonium salt was developed.

carbenes - cycloadditions - hydrolysis - rearrangements - stereoselective synthesis